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The first synthesis of 2-amino-1,4-dihydroquinolines

✍ Scribed by Guillaume Viault; Danielle Grée; Thierry Roisnel; Srivari Chandrasekhar; René Grée

Book ID
108283147
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
378 KB
Volume
65
Category
Article
ISSN
0040-4020

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✍ Farhat Rezgui; Pierre Mangeney; Alex Alexakis 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 260 KB

Asymmetric synthesis of dihydroquinolines by addition of organometallic reagents on a chiral 3-quinolinyl aminal was studied. 1,2-Adducts were obtained with good regio-and diastereoselectivity. The absolute configuration for 1,2-adducts was determined by X-ray analysis and for 1,4-adducts by chemica