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Asymmetric synthesis of 1,2- and 1,4-dihydroquinolines

✍ Scribed by Farhat Rezgui; Pierre Mangeney; Alex Alexakis

Book ID
104261955
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
260 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Asymmetric synthesis of dihydroquinolines by addition of organometallic reagents on a chiral 3-quinolinyl aminal was studied. 1,2-Adducts were obtained with good regio-and diastereoselectivity. The absolute configuration for 1,2-adducts was determined by X-ray analysis and for 1,4-adducts by chemical correlation.

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