The first stable member of the 8-oxatricyclo[4.3.0.0.7,9]Nona-2,4-diene ring-system
β Scribed by Ronald N. Warrener; Richard A. Russell; Richard Y.S. Tan
- Book ID
- 104245665
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 208 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
Homologucs and hoterologues of cyclooctatetraene (COT) are available by replacement of the T-bonds by the appropriate 3-membered ring. Bicyclo[6.1.O]nona-2,4,6-triene (1) (homo-COT), like COT itself is known to be in equilibrium with its ~II valence isomeric form, although the proportion of isomer (3) [(l):(3) = 4500:111 is too low to be detected by normal spectroscopic -. __
π SIMILAR VOLUMES
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Recently, Cargill and coworkers1 have reported that irradiation of antitricyclo[5.2.0.0 285]nona-3,8-dien-9-one(I)l'2 in methylenechloride with "black-CI, lights" gives homocubane as a major product. However, it may be expected that