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The first silver(I) nitrate π-complexes with unsaturated organosilicons: Synthesis and structural characterization of [Ag(DADPS)xNO3] (DADPS = diallyldiphenylsilane, x = 0.75; 1)

✍ Scribed by Krzysztof Trzebuniak; Bartosz Zarychta; Volodymyr Olijnyk


Book ID
113806121
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
574 KB
Volume
1006
Category
Article
ISSN
0022-2860

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Reactions of Ag 4 X 4 (Ph 3 P) 4 (X = Br, I) with 1,3-bis(diphenylphosphine)methane (dppm) ligand under microwave heating conditions afforded two asymmetric silver(I) dimers of the type [Ag 2 (l-X) 2 (ldppm)(PPh 3 ) 2 ], X = Br(1), I(2), with butterfly-shaped dinuclear cores. The molecular structure