Microwave-assisted synthesis, crystal st
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Geng-Geng Luo; Rui-Bo Wu; Di Sun; Jian-Hua Chen; Na Zhang; Rong-Bin Huang; Li-Ro
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Article
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2009
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Elsevier Science
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English
⚖ 878 KB
Reactions of Ag 4 X 4 (Ph 3 P) 4 (X = Br, I) with 1,3-bis(diphenylphosphine)methane (dppm) ligand under microwave heating conditions afforded two asymmetric silver(I) dimers of the type [Ag 2 (l-X) 2 (ldppm)(PPh 3 ) 2 ], X = Br(1), I(2), with butterfly-shaped dinuclear cores. The molecular structure