The First Reaction of the N2 Ligand with Bases; Reduction of Coordinated Dinitrogen by Nucleophilic Attack
β Scribed by Professor Dr. Dieter Sellmann; Dr. Woldemar Weiss
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 216 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
An essential process in nitrogen fixation is cleavage of molecular nitrogen. [1] Several studies using model systems have confirmed that metal nitrides can be formed from coordinated dinitrogen providing that at least six electrons are available to formally reduce the N 2 unit to two N 3Γ ligands. [
The crystal structure of a copper(II) complex of 2acetylpyridine 3-piperidylthiosemicarbazone, [Cu(Acpip) 2 ], indicates a tridentate, monoanionic ligand (i. e., pyridine nitrogen, imine nitrogen and thiolato sulfur atoms) and a bidentate, monanionic ligand (i. e., imine nitrogen and thiolato sulfur