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The First Ozonide of a Phosphorus Oxide—Preparation, Characterization, and Structure of P4O18

✍ Scribed by Anton Dimitrov; Burkhard Ziemer; Wolf-Dietrich Hunnius; Manfred Meisel


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
206 KB
Volume
42
Category
Article
ISSN
0044-8249

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✍ Sara Reiser; Gunther Brunklaus; Jung Hoon Hong; Jerry C. C. Chan; Hellmut Eckert 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 145 KB

(CuI)(3)P(4)S(4) is obtained by reaction of stoichiometric amounts of CuI, P, and S in evacuated silica ampoules. The yellow compound consists of monomeric beta-P(4)S(4) cage molecules that are separated by hexagonal columns of CuI. (CuI)(3)P(4)S(4) crystallizes isotypic to (CuI)(3)P(4)Se(4) in the