Telefax: Int. code + (617) 253-7030 e-mail: ccummins(cr rnit.edu [\*\*I This work was supported by a National Science Foundation CAREER award to C . C. C . (CHE-9501YY2) and by the MlTDepartmenl ofthemistry. Michael C(CD,),CH,), 33.36 (m. C(CD3)2CH3). 21.30 (4. IJIl'rU ( ' 6 H , M ~~2 ) : "P NMR
Synthesis and Structure of the First Transition Metal Complex of a Phosphorus Compound with a Direct λ3P—λ5P Bond
✍ Scribed by Prof. John W. Gilje; Dr. William S. Sheldrick; Dr. Norbert Weferling; Prof. Dr. Reinhard Schmutzler
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 213 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
An ampule reaction between Mo and PCl 5 at 200 °C yielded (PCl 4 ) 2 [Mo 2 Cl 10 ], the first ternary compound in Mo±P±Cl system. Single crystal X-ray diffraction gave a triclinic unit cell: a = 6.870(1), b = 8.892(2), c = 9.423(2) A Ê , α = 100.24(2), b = 95.55(2), c = 96.12(2)°(V = 559.3(2) A Ê 3
coii,tiinl. I' is the kinematic viscosity, and C\* is the catalyst concentration (1.0 x l o -" M). 17 was determined from the slope of Levich plot I'rz = 1.7 x 10.' A. The kinetic viscosity II was found to be 4.8 x em's-'. and the diffusion constant D = 2.4 x ems-' for the observed solvent sytein wi