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The First Octahedral Zintl Ion: Sn as a Ligand in [Sn6{Cr(CO)5}6]2−

✍ Scribed by Dipl.-Chem. Berthold Schiemenz; Prof. Dr. Gottfried Huttner

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
313 KB
Volume
32
Category
Article
ISSN
0044-8249

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The 1,3-Sn2O2-Heterocycle as a Ligand in Organometallic Compounds – Dimerization of the Inidene Species [{(CO)5M}2SnOR]– (M = Cr, W)
✍ Peter Kircher; Gottfried Huttner; Katja Heinze; Laszlo Zsolnai 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 500 KB

## Dimerized inidene complexes [(CO) 5 M … Ϫ Sn(OR) … Ϫ M(CO) 5 ] 2 2system, which characterizes monomeric inidene species still prevalent in the dimeric species 1. The (M = Cr, W; R = Et, iPr), 1, are obtained from [{(CO) 5 M} 2 SnCl 2 ] 2- by different routes. Dimerization occurs via alkoxy-don