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[{(CO)5Cr}6Ge6]2−, A Molecular Organometallic Derivative of the Unknown Zintl Ion [Ge6]2−

✍ Scribed by Peter Kircher; Gottfried Huttner; Katja Heinze; Gerd Renner


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
105 KB
Volume
37
Category
Article
ISSN
0044-8249

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[V15Ge6O42S6(H2O)]12–, a Thiogermanatopo
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The new compound [Co(tren)(trenH 2 )] 2 [{Co(tren)} 2 -V 15 Ge 6 O 42 S 6 (H 2 O)]•9H 2 O [1, tren = tris(2-aminoethyl)amine] has been obtained under solvothermal conditions and features the unique thiogermanatovanadatopolyoxoanion [V IV 15 Ge IV 6 O 42 S 6 (H 2 O)] 12-as the main structural motif.