Professor Manfred Weidenbruch zum 60. Geburtstag gewidmet Mit der Synthese von [{(CO) 5 Cr} 6 Sn 6 ] 2À [1] war gezeigt worden, daû Cluster, die ausschlieûlich aus Hauptgruppenelementen zusammengesetzt sind, aus metallorganischen Vorstufen gebildet werden können, wodurch die Cluster zugleich in eine
✦ LIBER ✦
[{(CO)5Cr}6Ge6]2−, A Molecular Organometallic Derivative of the Unknown Zintl Ion [Ge6]2−
✍ Scribed by Peter Kircher; Gottfried Huttner; Katja Heinze; Gerd Renner
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 105 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0044-8249
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[V15Ge6O42S6(H2O)]12–, a Thiogermanatopo
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The new compound [Co(tren)(trenH 2 )] 2 [{Co(tren)} 2 -V 15 Ge 6 O 42 S 6 (H 2 O)]•9H 2 O [1, tren = tris(2-aminoethyl)amine] has been obtained under solvothermal conditions and features the unique thiogermanatovanadatopolyoxoanion [V IV 15 Ge IV 6 O 42 S 6 (H 2 O)] 12-as the main structural motif.