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The First Observation of γ-Sila-Pummerer Rearrangement

✍ Scribed by Mikina, Maciej

Book ID
118144801
Publisher
Taylor and Francis Group
Year
2013
Tongue
English
Weight
150 KB
Volume
188
Category
Article
ISSN
1042-6507

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1-Phenylthio-1-(trimethylsiloxy)cyclopro
1-Phenylthio-1-(trimethylsiloxy)cyclopropanes via the sila-Pummerer rearrangement
✍ M. Bhupathy; Theodore Cohen 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 267 KB

This first study of the sila-Pummerer rearrangement in a cyclopropane system reveals that several 1 -trimethylsiloxy-7 -(phenylthio)cyclopropanes can be prepared stereoselectively through putative sulfur-stabilized carbocationic intermediates.