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The sila-Pummerer rearrangement of 3,3-dimethyl-3-silathiane S-oxide

✍ Scribed by Svetlana V. Kirpichenko; Elena N. Suslova; Alexandr I. Albanov; Bagrat A. Shainyan


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
189 KB
Volume
40
Category
Article
ISSN
0040-4039

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Stereoespecific syntheses of 2,3-dimethy
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The stereoespecific syntheses of cis-and trans-2,3-dimethyl-1,4-oxathian, their diastereomeric --. S-oxides and their S-dioxide derivatives are reported. The key step in the synthetic pathways is the cyclization ofa 2-hydroxyalkyl vinylsulphoxide, by intramolecular conjugated addition with retention