A comparison of reactivity of (EtO)2P(O)
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Piotr BaΕczewski; Tomasz BiaΕas; Aldona Szadowiak
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Article
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2003
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John Wiley and Sons
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English
β 76 KB
## Based on competitive reactions and 1 H NMR measurements, it was found that (EtO) 2 P(O)CH 2 I is at least 2-3 orders of magnitude less reactive than other non-phosphorus iodides of the EWG-CH 2 I type (EWG = NC, COOMe, 4-Br-C 6 H 4 CO). MeSCH 2 I turned out to be totally unreactive in the title