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The first observation of splitting by a "peripheral" substituent in a radical cation containing a tetravalent phosphorus atom

✍ Scribed by Rieke, Reuben D.; White, C. Kenneth


Book ID
127319306
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
415 KB
Volume
42
Category
Article
ISSN
0022-3263

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A comparison of reactivity of (EtO)2P(O)
✍ Piotr BaΕ‚czewski; Tomasz BiaΕ‚as; Aldona Szadowiak πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 76 KB

## Based on competitive reactions and 1 H NMR measurements, it was found that (EtO) 2 P(O)CH 2 I is at least 2-3 orders of magnitude less reactive than other non-phosphorus iodides of the EWG-CH 2 I type (EWG = NC, COOMe, 4-Br-C 6 H 4 CO). MeSCH 2 I turned out to be totally unreactive in the title