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The First Highly Enantioselective Catalytic Diphenylzinc Additions to Aldehydes: Synthesis of Chiral Diarylcarbinols by Asymmetric Catalysis

โœ Scribed by Huang, Wei-Sheng; Pu, Lin


Book ID
124095778
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
75 KB
Volume
64
Category
Article
ISSN
0022-3263

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Readily available chiral tridentate ligand & catalyzes the highly Si-face selective addition of diethyl-, di-n-propylzinc and, more significantly, of divinylzinc to aromatic and aliphatic aldehydes whereas bidentate ligands 11 and u exert a topologically reversed catalytic bias. Asymmetric formatio