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ChemInform Abstract: The First Highly Enantioselective Catalytic Diphenylzinc Additions to Aldehydes: Synthesis of Chiral Diarylcarbinols by Asymmetric Catalysis.

โœ Scribed by Wei-Sheng Huang; Lin Pu

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Dramatic Temperatur
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โœ Huichang Zhang; Kin Shing Chan ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

Dramatic Temperature Effect in Asymmetric Catalysis in the Enantioselective Addition of Diethylzinc to Aldehydes. -The enantioselectivity of the addition of Et 2 Zn to aryl aldehydes in the presence of catalytic amounts of a chiral pyridyl-phenol ((S)-MPBP) is found to depend heavily on temperature