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The first d0 metallooxaziridines. Amination of olefins

✍ Scribed by Liebeskind, Lanny S.; Sharpless, K. Barry; Wilson, Robert D.; Ibers, James A.


Book ID
120044931
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
397 KB
Volume
100
Category
Article
ISSN
0002-7863

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A wide variety of nucleophiles have been observed to add to olefins complexed to palladium. 2 When the nucleophile, e.g. acetate, is added externally trana-addition appears to take place. 2,3.4,5 With aryl-and alkylpalladium compounds, where the aryl and alkyl groups are essentially covalently bou