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Palladium(0)-catalyzed amination of allylic natural terpenic functionalized olefins

โœ Scribed by Houssame, Soufiane ;Anane, Hafid ;Firdoussi, Larbi ;Karim, Abdellah

Book ID
111488053
Publisher
Walter de Gruyter GmbH
Year
2008
Tongue
English
Weight
909 KB
Volume
6
Category
Article
ISSN
2391-5420

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The palladium-catalyzed alkoxycarbonylation of allyl carbonates and allyl chlorides derivatives from terpenic olefins was carried out under atmospheric pressure of carbon monoxide and at moderate temperature. The reaction offers a very good method for the preparation of new โค, โฅ-unsaturated esters a

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Synthesis of potential antiparisitic 5'-aminonucloesides such as 10 could not be accomplished using standard amination procedures. Palladium(0)-catalyzed amination of cyclic allylic acetates with benzylamine or phthalimide gave the corresponding protected amines. This method was then extended to the