The First Cadmium-Specific Enzyme
β Scribed by Henry Strasdeit
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 70 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
β¦ Synopsis
Scheme 4. General dendralene synthesis according to Sherburn et al.
hydrocarbons 37 are released on demand in good yields by high-temperature pyrolysis. As no solvent is required in these cheletropic reactions, the workup is clearly made easier. The dendralenes 37 obtained, up to [8]dendralene (n 6), have been completely characterized by the usual spectroscopic and analytical methods and can, although they have a tendency to polymerize, be manipulatedΓthe deciding prerequisite for the study of their reactivity.
π SIMILAR VOLUMES
A new model for general enzyme catalysis challenges the idea that transition state complementarity of enzyme active sites to the reactions they catalyze is the sole source of their catalytic efficacy. The "shifting specificity" model rejects the widely held view that strong interactions of the enzym