✦ LIBER ✦

The first band in the He(I) photoelectron spectrum of the CH2Cl free radical

✍ Scribed by Lester Andrews; John M. Dyke; Neville Jonathan; Noureddine Keddar; Alan Morris; Abed Ridha

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 439 KB
Volume: 97
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87190-5

No coin nor oath required. For personal study only.

✦ Synopsis

The fluorine atom reaction wvirh CH3Q provides rhe CHzCl free radical for observarion of a srructured phoroelectron band ar 8.88 k 0.01 eV terrical ionizadon energy with 1020 5 40 cm-l vibrational intervals. This spacing is appropriare for the C-Cl fundamental in CHICI* based on increase (p-p) n bonding in the cation as compared to rhe free radical.

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