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The first asymmetric synthesis of the naturally occurring (+)-Kotanin and the assignment of its absolute configuration

✍ Scribed by Guo-Qiang Lin; Min Zhong

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 241 KB
Volume: 8
Category: Article
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(97)00117-1

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✦ Synopsis

The first asymmetric synthesis of the naturally occurring (+)-Kotanin is described. The key steps involve the intramolecular oxidative coupling of the cyanocuprate intermediate and the Fries rearrangement. The absolute configuration of (+)-Kotanin was assigned as aS by CD spectroscopic method. (~) 1997

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