𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The fast atom bombardment mass spectra of furyl and thienyl silanes and germanes in comparison with their electron impact mass spectra

✍ Scribed by I. Mažeika; S. Grīnberga; M. Gavars; A. P. Gaukhman; N. P. Erchak; E. Lukevics

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
306 KB
Volume
28
Category
Article
ISSN
1076-5174

No coin nor oath required. For personal study only.

✦ Synopsis

The interaction of the s electron system of furyl and thienyl substituents with the silicon (or germanium) atom is less significant in fragmentation under fast atom bombardment than under electron impact. Under fast atom bombardment the primary fragmentation of the title compounds is determined by steric influence of the heteroaromatic substituents.

📜 SIMILAR VOLUMES

Comparisons between electron impact and
Comparisons between electron impact and fast atom bombardment mass spectra of some triphenylphosphonium and triphenylarsonium salts
✍ Miller, Jack M.; Ni, Jinsong 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 594 KB

The electron impact (El) mass spectra of alkyltriphenylphosphonium and alkyltriphenylarsonium salts were compared with fast atom bombardment (FAB) mass spectra in a 3-nitrobenzyl alcohol matrix. It is clearly demonstrated that FAB is an effective ionization method compared with El for analysis of th

Odd-electron molecular ion and loss of t
Odd-electron molecular ion and loss of toluene in fast atom bombardment mass spectra of some carotenoids
✍ Salvatore Caccamese; Domenico Garozzo 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 268 KB

## Abstract Positive‐ion fast atom bombardment (FAB) and __B/E__ linked scan FAB mass spectra of seven carotenoids are reported. In all cases the M ^+·^ ions are observed, and the [M + H]^+^ ions are absent in the hydrocarbons and weak in the oxygenated compounds. The usefulness of __B/E__ linked s