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The facile dealkylation of phosphonic acid dialkyl esters by bromotrimethylsilane

✍ Scribed by Charles E. McKenna; Melvin T. Higa; Neil H. Cheung; Marie-Claire McKenna

Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
304 KB
Volume
18
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Stereoselective synthesis of enantiopure
Stereoselective synthesis of enantiopure cyclic Ξ±-aminophosphonic acids: Direct observation of inversion at phosphorus in phosphonate ester silyldealkylation by bromotrimethylsilane
✍ Vladimir A. Alfonsov; Charles E. McKenna; Evgenia V. Bayandina; Boris A. Kashemi πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 179 KB

## Abstract The paper describes a simple, direct synthesis of enantiopure cyclic α‐aminophosphonic acids on the basis of silyldealkylation and followed by hydrolysis of the parent diastereoisomeric cyclic 1,4,2‐oxazaphosphorines, which have been obtained by intramolecular stereospecific nucleophili