✦ LIBER ✦

The explosive reaction of carbon monoxide and oxygen at 973 and 1048 K

✍ Scribed by S. Ahmed; M. H. Back

Publisher: John Wiley and Sons
Year: 1986
Tongue: English
Weight: 783 KB
Volume: 18
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550180707

No coin nor oath required. For personal study only.

✦ Synopsis

Conditions leading to an explosive reaction of carbon monoxide and oxygen in the presence of small amounts of water have been examined at temperatures of 973 and 1048 K. Carbon monoxide and water were formed in the presence of oxygen by reaction with a thin film of carbon deposited on a quartz vessel. The carbon provided a reactive and reproducible surface, giving a consistent rate of termination and thus allowing a quantitative description of the conditions a t the explosion in the region of the first limit. Calculations of the rates of the various branching and termination reactions a t the onset of the explosion showed that the simple mechanism described earlier was still adequate to explain the reaction at temperatures up to 1050 K. From experiments with inert gases the transition from the first explosion limit to the region of the second explosion limit was demonstrated.

📜 SIMILAR VOLUMES

Kinetics and mechanism of the explosive

Kinetics and mechanism of the explosive reaction of carbon monoxide and oxygen

✍ S. Ahmed; M. H. Back 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 975 KB

A new technique is described for quantitative measurement of the conditions of reactant concentration at ignition in mixtures of carbon monoxide and oxygen. A thin film of carbon covering the surface of a quartz reaction vessel reacted with oxygen to form carbon monoxide and small quantities of wate

Free-radical reactions in glow and explo

Free-radical reactions in glow and explosion of carbon monoxideoxygen mixtures

✍ G. Von Elbe; Bernard Lewis 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 1014 KB

Reaction of carbon monoxide with ozone a

Reaction of carbon monoxide with ozone and oxygen atoms

✍ Sidney Toby; Shailesh Sheth; Frina S. Toby 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 390 KB

The reaction between ozone and carbon monoxide was reinvestigated in the range of 80-160°C. The previously reported rate law -d[O,l/dt = k.[o,][Co] + k,[0,l2 was confirmed and simulated using a mechanism based on an impurity-initiated chain reaction. When the CO was sufficiently purified, k, tended

A photoelectric study of the low pressur

A photoelectric study of the low pressure explosion limit of the wet carbon monoxide-oxygen reaction

✍ J.W. Linnett; B.G. Reuben; T.F. Wheatley 📂 Article 📅 1968 🏛 Elsevier Science 🌐 English ⚖ 634 KB

The so.called low pressure glow and explosion limits of the water-cataiysed reaction between carbon monoxide and oxygen have been studied using a photomultiplier to obtain light intensity/time graphs. The results show no sign of a glow limit, and little discontinuity at the explosion limit. The effe

Chromatographic investigation of the oxy

Chromatographic investigation of the oxygen exchange reaction between carbon monoxide and carbon dioxide

✍ W. D. Smith; H. A. Deans 📂 Article 📅 1974 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 868 KB

Photolysis and Radiolysis of Carbon Mono

Photolysis and Radiolysis of Carbon Monoxide in the Gaseous, Liquid, and Solid State at 298 °K, 77 °K, and 20.4 °K

✍ Prof. Dr. W. Groth 📂 Article 📅 1968 🏛 John Wiley and Sons 🌐 English ⚖ 104 KB 👁 1 views