The exo-anomeric effect in relation to polysaccharide conformation in solution
β Scribed by Terence J. Painter
- Book ID
- 103550324
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 148 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0144-8617
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Abstrack The crystal stmctum and sohrfion conformation of rhe chiral mono-rrehaIo-15-cmn.n 5 1 shows what is pmbab& the first case of a disacchaddic shucture where the anomenc effect does not dominate. This unexpected conjnmational change seems to be a geneml tendency in L2'-po&elhyIene glycoI subsl
Stereoselective Sulfoxidation of Ξ±-Mannopyranosyl Thioglycosides: The exo-Anomeric Effect in Action. -In analogy to previous results Ξ±-thioglycoside (I) undergoes stereoselective oxidation affording predominantly the (R)-sulfoxide (II) as a consequence of the exo-anomeric effect. Its structure is c