✦ LIBER ✦

The exo-anomeric effect does not govern the conformation of some 2,2′-O-substituted α,α′-trehalose derivatives. Solid state and solution evidences.

✍ Scribed by F.H. Cano; J.L.G. de Paz; C. Foces-Foces; J. Jiménez-Barbero; M. Martín-Lomas; S. Penadés; C. Vicent

Book ID: 104203886
Publisher: Elsevier Science
Year: 1993
Tongue: French
Weight: 466 KB
Volume: 49
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)86310-9

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✦ Synopsis

Abstrack The crystal stmctum and sohrfion conformation of rhe chiral mono-rrehaIo-15-cmn.n 5 1 shows what is pmbab& the first case of a disacchaddic shucture where the anomenc effect does not dominate. This unexpected conjnmational change seems to be a geneml tendency in L2'-po&elhyIene glycoI subslihtled lmhalose den'vatives.