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The existence of adamantene

โœ Scribed by Burns, William; McKervey, M. Anthony


Book ID
120325392
Publisher
The Royal Society of Chemistry
Year
1974
Tongue
English
Weight
109 KB
Volume
21
Category
Article
ISSN
0022-4936

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Adamantene
โœ A.H. Alberts; J. Strating; Hans Wynberg ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 150 KB

The possibility of existence of 1,2-dehydroadamantene or ademantene II is an intriguing question in adsmantane chemistry (1). Ademsntene is expected to be highly strained because the p-orbitals of the 1,2-double bond cannot overlap without considerable deformation of the rigid

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The facile ring closure' of bicyclononane dlcarboxylic acid to 2-oxo-adamantane carboxylic acid (I, R=H) opened a new route to 1,2-disubstituted adamantsnes. We have

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A(AGI: 4 f l kcal.mol.' Scheme 1. Stability sequence ofcations (1) to (6); D(R@ X"') values taken from l3bl.