The possibility of existence of 1,2-dehydroadamantene or ademantene II is an intriguing question in adsmantane chemistry (1). Ademsntene is expected to be highly strained because the p-orbitals of the 1,2-double bond cannot overlap without considerable deformation of the rigid
Possible precursors of adamantene
โ Scribed by A.H. Alberts; Hans Wynberg; J. Strating
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 199 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
The facile ring closure' of bicyclononane dlcarboxylic acid to 2-oxo-adamantane carboxylic acid (I, R=H) opened a new route to 1,2-disubstituted adamantsnes. We have
๐ SIMILAR VOLUMES
A(AGI: 4 f l kcal.mol.' Scheme 1. Stability sequence ofcations (1) to (6); D(R@ X"') values taken from l3bl.
A new sesquiterpene named panal was isolated from Panellus stipticus. Upon treatment with salts of ammonia or the luminous mushroan primary anines, panal yields a substance(s) which emits light in the presence of Fe2+, On the basis of chemical and spectroscopic data, the structure 1 panal, excluding