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Possible precursors of adamantene

โœ Scribed by A.H. Alberts; Hans Wynberg; J. Strating


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
199 KB
Volume
14
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


The facile ring closure' of bicyclononane dlcarboxylic acid to 2-oxo-adamantane carboxylic acid (I, R=H) opened a new route to 1,2-disubstituted adamantsnes. We have


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Adamantene
โœ A.H. Alberts; J. Strating; Hans Wynberg ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 150 KB

The possibility of existence of 1,2-dehydroadamantene or ademantene II is an intriguing question in adsmantane chemistry (1). Ademsntene is expected to be highly strained because the p-orbitals of the 1,2-double bond cannot overlap without considerable deformation of the rigid

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A new sesquiterpene named panal was isolated from Panellus stipticus. Upon treatment with salts of ammonia or the luminous mushroan primary anines, panal yields a substance(s) which emits light in the presence of Fe2+, On the basis of chemical and spectroscopic data, the structure 1 panal, excluding