A new radical cation having the methyl carbene type structure [CH3CHCIH]" has been characterized in the gas phase. It is readily generated by the dissociative ionization [CH3CHClC02H]" + C02+[CH3CHC1H]". Its enthalpy of formation has been estimated to be 951 kJ mol-l, close to that of [CH3CH2CI]". T
β¦ LIBER β¦
The ethyl halides: Stable neutral and radical cation isomers [C2, H2, X] where X = F, Cl, Br, I
β Scribed by Marcia C. Blanchette; John L. Holmes; F. P. Lossing
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- English
- Weight
- 768 KB
- Volume
- 22
- Category
- Article
- ISSN
- 1076-5174
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Stable C2H5X+Λ (X=Cl, Br) radical cation
β
John L. Holmes; Peter C. Burgers; Johan K. Terlouw; Helmut Schwarz; Bernhard Cio
π
Article
π
1983
π
John Wiley and Sons
π
English
β 369 KB
Hypercoordinated Organotin(IV) Halides C
β
Richard A. Varga; Adina Rotar; Markus SchΓΌrmann; Klaus Jurkschat; Cristian Silve
π
Article
π
2006
π
John Wiley and Sons
π
English
β 322 KB
π 1 views
Synthesis of [RuX(CO){Ξ·2-C,N-C6H4C(H)=NC
β
KevinΒ R. Flower; RobinΒ G. Pritchard; JohnΒ E. Warren
π
Article
π
2003
π
John Wiley and Sons
π
English
β 261 KB
π 1 views
Fragmentation of alkylmercury halides un
β
D.V. Zagorevskii; M.Sh. Mikeladze; Yu.S. Nekrasov; N.I. Rayevsky; Yu.N. Sukharev
π
Article
π
1988
π
Elsevier Science
π
English
β 298 KB
Infrared spectra of complex ions of the
β
D.H. Brown; D.R. MacSween; D.W.A. Sharp
π
Article
π
1969
π
Elsevier Science
β 147 KB
Raman spectroscopic studies of the rotat
β
Anke JΓ€hn; Karla Schenzel; Robert Zink; Karl Hassler
π
Article
π
1998
π
John Wiley and Sons
π
English
β 332 KB
π 1 views
The Raman vibrational spectra of the heptamethyltrisilanes with X = H, F, Cl, Br, XMe 2 SiSiMe 2 SiMe 3 , C 6 H 5 and unambiguously prove the presence of two rotamers, anti and gauche, in the liquid state. With variable-OCH 3 , temperature Raman vibrational spectroscopy, enthalpy di β erences between