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Fragmentation of alkylmercury halides under electron impact and the structure of the C2H4HgX+ ion (X = Cl, Br, I) in the gas phase

✍ Scribed by D.V. Zagorevskii; M.Sh. Mikeladze; Yu.S. Nekrasov; N.I. Rayevsky; Yu.N. Sukharev; Yu.A. Borisov; S.Yu. Sil'vestrova; R.D. Rakhimov; A.I. Gren'; A.V. Mazepa; O.S. Timofeev


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
298 KB
Volume
348
Category
Article
ISSN
0022-328X

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MNDO study of fragmentations in mass spe
✍ Jan HruΕ‘Γ‘k; Martin Tkaczyk πŸ“‚ Article πŸ“… 1989 πŸ› John Wiley and Sons 🌐 English βš– 478 KB

## MNDO calculations of [C3H ,0]+' predict the parallel existence of both structures of radical cations of acetone (1) and propen-2-01 (2) in electron ionization spectra. The calculated heats of formation of 1+' (A@"Do = 783.2 kJ mol-' and of 2" (AflNDo = 649.8 kJ mol-') are in very good agreement