The results of some molecular-orbital caIculations on some transition-metal complexes according to a nove1 allvalence electron method are summarized. A comparison is made between the CalcuIated and experimental chargetransfer spectra. In addition, attention is drawn to the remarkable sequence of the
The Equivalent Orbital Method of Interpreting Photoelectron (PE) Spectra: Neopentane
โ Scribed by Dr. Werner Schmidt; Bernard T. Wilkins
- Publisher
- John Wiley and Sons
- Year
- 1972
- Tongue
- English
- Weight
- 345 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0044-8249
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โฆ Synopsis
The n-ionization energies['] of alkyl-substituted triketones, as determined by photoelectron spectroscopy, can also be discussed on the basis of the calculated geometry of dimethyltriketone.
๐ SIMILAR VOLUMES
X-ray photoelectron spectra arc presented of the vnlcnoe regions (O-40 eY binding energy) of the isoelectronic nnionn ClOz .md SO' -. I orbital calculations and availab The photoelectron lines are ess&ned on the basis of existing mnolcn,uIar e X-ray fluoretrccnce data. The intcnvities of thu phutoct
The higher homologues of n-alkanes H(CH2),H with N > -13 yield photoelectron spectra in which the (&-bands merge to form a double humped, unresolved C2,-band system in the interval of I = 15 to 25 eV [l]. It is shown that with the help of an equivalent bond orbital model one can derive a closed form