X-ray photoelectron spectra and molecular orbital interpretation of the valence region of ClO4− and SO42−
✍ Scribed by R. Prins; T. Novakov
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 396 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
X-ray photoelectron spectra arc presented of the vnlcnoe regions (O-40 eY binding energy) of the isoelectronic nnionn ClOz .md SO' -. I orbital calculations and availab The photoelectron lines are ess&ned on the basis of existing mnolcn,uIar e X-ray fluoretrccnce data. The intcnvities of thu phutoctcctron lines act qualitatively nccountcd for by considering r~olccular orbital coefficicnte, orbital degeneracies. and atomic orbital croza sections for ionization.
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The valence electron bands of.the'&phase X-ray ph&oelectron spectra were me&wed on acetonitrile and nitro-.' . . m&ant?. ft is shown that the:obscrved spectra can be interpreted successfully by co~p~~~~ with f$e Iie f photo-e&ran spectra and the results of &DO/Z c&ulations.
The results of some molecular-orbital caIculations on some transition-metal complexes according to a nove1 allvalence electron method are summarized. A comparison is made between the CalcuIated and experimental chargetransfer spectra. In addition, attention is drawn to the remarkable sequence of the
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