The enzymic synthesis of O-α-d-glucopyranosyl (1 → 6)-2-amino-2 -deoxy-d-glucopyranose and its N-acetyl derivative
✍ Scribed by Anthony L. Tarentino; Frank Maley
- Book ID
- 118846359
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- English
- Weight
- 550 KB
- Volume
- 130
- Category
- Article
- ISSN
- 0003-9861
No coin nor oath required. For personal study only.
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The synthesis of the glycosyl-mya-inositol l-phosphates 1 and 2 and of the glycosyl-myoinositol 1,2-(cyclic phosphate) 3, starting from previously synthesized intermediates, is reported. Compound 3 was found to display proliferative effects on the early developing inner ear of chick embryo.
## Crystals of the tetrasaccharide, (2,3,4,6-tetra-0acetyl-fi-D-ghxopyranosyl~-(1 + 3)-[2,3,4,6-tetra-O-acetyI+LD-gIucopyranosyI-(1 --t 6)]-(2,4-di-0-acetyl-g\_D-glucopyranosyl)-1 --) 3)-1,2,4,6-tetrad-acetyl$?-n-ghicopyranose, belong to tge monoclinic system, space group P2,, with a = 12.709(4),