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The enol form of (+)-(1R,4R)-3-benzoyl­camphor

✍ Scribed by Niemeyer, Mark ;Gan, Min


Book ID
104484595
Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
232 KB
Volume
61
Category
Article
ISSN
1600-5368

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The diketo form of (+)-(1R,4R)-3-benzoyl
✍ Seo, Jang Woo ;Niemeyer, Mark 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 204 KB

Molecules of the title compound, (+)-(1R,4R)-3-benzoyl-1,7,7trimethylbicyclo[2.2.1]heptan-2-one, C 17 H 20 O 2 , crystallize in the diketo form. One of the carbonyl groups is involved in a weak intramolecular C-HÁ Á ÁO interaction [CÁ Á ÁO = 2.778 (3) A ˚]. 3-Benzoylcamphor is a rare example of a st