The energy dependence of the reaction of N+2 with CS2
โ Scribed by R. Passarella; Xiaolin Yang; R.G. Keesee; A.W. Castleman Jr.
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 366 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0168-1176
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The title reaction was studied by the direct time-resolved laser-induced lluorescence method at room temperature. The rate constants for the forward and reverse reactions were measured to be (1.92 0.5) x lo-" cm3 molecule-' s-l and (7.4&2.5)x IO4 s-', respectively. The rate constant forthe reaction
A steady-state system involvmg phato~s~ of HONO asa source of OH was used to ~~e5trgate the reaction of OH wtth CS2 at 1 atm and 295 Ii. In the presence of 02 (240 Torr) a rapid reaction of OH with CSz occurs giving OCS. At lower Oz concentrafionq 0C.S formation ceases. fn au the overall rate consta