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The enantiodivergent total synthesis of natural and unnatural enantiomers of theobroxide

✍ Scribed by Takashi Kamikubo; Kunio Ogasawara


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
217 KB
Volume
36
Category
Article
ISSN
0040-4039

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## Abstract The accumulation of psychosine (galactosyl sphingosine) has been associated with the pathogenesis of Krabbe disease; however, the exact mechanism of its cytotoxicity remains unclear. Herein, we describe the synthesis of the unnatural enantiomer of erythro‐sphingosine, psychosine, and re