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The Electrophilic Substitution of Arenes: Is the π Complex a Key Intermediate and What Is Its Nature?

✍ Scribed by Dieter Lenoir

Publisher
John Wiley and Sons
Year
2003
Weight
58 KB
Volume
34
Category
Article
ISSN
0931-7597

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✍ Dieter Lenoir; Cinzia Chiappe 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 236 KB 👁 1 views

The pi complexes first formed as essential intermediates from alkenes, alkynes, and allenes with bromine have been investigated in different solvents by UV-spectroscopy in combination with stopped-flow techniques allowing the determination of the equilibrium constants, K(f). Using alkenes with steri