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The Electrophilic Substitution of Arenes: Is the π Complex a Key Intermediate and What is Its Nature?

✍ Scribed by Dieter Lenoir

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
127 KB
Volume
42
Category
Article
ISSN
0044-8249

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✦ Synopsis

Chemistry is the science of the ele- mental metamorphosis of matter. Its fundamental principle is not the existing substance, but rather its past and future.

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The pi complexes first formed as essential intermediates from alkenes, alkynes, and allenes with bromine have been investigated in different solvents by UV-spectroscopy in combination with stopped-flow techniques allowing the determination of the equilibrium constants, K(f). Using alkenes with steri