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The electronic structures of phosphorus sulphide (P4S4) and arsenic sulphide (As4S4), and a comparison with sulphur nitride (N4 S4)

โœ Scribed by Michael H. Palmer; Robert H. Findlay


Book ID
119115994
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
764 KB
Volume
104
Category
Article
ISSN
0166-1280

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(CuI)3P4S4: Preparation, Structural, and
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(CuI)(3)P(4)S(4) is obtained by reaction of stoichiometric amounts of CuI, P, and S in evacuated silica ampoules. The yellow compound consists of monomeric beta-P(4)S(4) cage molecules that are separated by hexagonal columns of CuI. (CuI)(3)P(4)S(4) crystallizes isotypic to (CuI)(3)P(4)Se(4) in the