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The electronic structure of the metal-to-ligand charge-transfer states of M(bpy)2+3 (M = Fe, Ru, Os)

✍ Scribed by James Ferguson; Fritz Herren

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
363 KB
Volume
89
Category
Article
ISSN
0009-2614

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✦ Synopsis

New spectroscopic absorption and luminescence data for the ions M(bpy)~ + @I = Fe, Ru, Os) provide the basis for a theoretical model of the electronic structure of these ions. An important aspect of the model is the essential localization of the triplet states, in contrast to the singlet states which are delocalized. The model accounts very well for the new and existing spectroscopic data.

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