𝔖 Bobbio Scriptorium
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The electronic structure of the first-row transition-metal diborides

✍ Scribed by David R. Armstrong

Publisher
Springer
Year
1983
Tongue
English
Weight
659 KB
Volume
64
Category
Article
ISSN
1432-2234

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## Abstract Lithiated 4‐methyl‐2‐[(trimethylsilyl)amino]pyridine (Ap^TMS^H) undergoes a salt metathesis reaction with [ScCl~3~(thf)~3~] and FeCl~3~, at low temperature in thf, to yield the homoleptic complexes [Sc(Ap^TMS^)~3~] (1) and [Fe(Ap^TMS^)~3~] (2). An analogous reaction with MnCl~2~, CoCl~2