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Valence 4pfunctions for the first-row transition metal atoms

✍ Scribed by Hiroshi Tatewaki; Toshikatsu Koga; Shigeyoshi Yamamoto

Publisher
Springer
Year
2000
Tongue
English
Weight
106 KB
Volume
105
Category
Article
ISSN
1432-2234

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Slater type orbital (STO) basis sets for the atoms Sc-Zn have been derived using a technique based on the distance between subspaces. The accuracy for several properties of these basis sets has been tested. Basis sets studied are of both single-and double-zeta sizes, although this technique can be g

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## Abstract Lithiated 4‐methyl‐2‐[(trimethylsilyl)amino]pyridine (Ap^TMS^H) undergoes a salt metathesis reaction with [ScCl~3~(thf)~3~] and FeCl~3~, at low temperature in thf, to yield the homoleptic complexes [Sc(Ap^TMS^)~3~] (1) and [Fe(Ap^TMS^)~3~] (2). An analogous reaction with MnCl~2~, CoCl~2