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The electronic structure and orientation of the surface methoxy species on Ni(111)

✍ Scribed by J.L. Erskine; A.M. Bradshaw


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
376 KB
Volume
72
Category
Article
ISSN
0009-2614

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✦ Synopsis


Recewcd 7 March 1980 Photoelectron spectra of the methouy species formed by the decomposltrcm of methanol on mckcI( 11 I) mdtcate that the C-O-nrchel bond IS normal or nearly normal to the metal surface Thts structural assignment for the adsorbste complex IS consrstent \lth new photoelrctron data usmg lmrnriy polarwed SYflchrotron radtation.


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We report the observation of a vibrational overtone for an adsorbate on a single crystal surface by high-resolution vibrational spectroscopy. A very weak absorption band at 20 17 cm-' is identified as the first overtone of the C-O stretching fundamental (at IO27 cm-') of . The anharmonic shift in th