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The electronic structure and copolymerization parameters of peroxide monomers

✍ Scribed by B.L. Rublev; L.S. Chuiko


Book ID
118966524
Publisher
Elsevier Science
Year
1980
Weight
383 KB
Volume
22
Category
Article
ISSN
0032-3950

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Structure and reactivity of peroxide mon
✍ S. A. Voronov; Eu. M. Kiselyov; S. S. Minko; O. G. Budishevska; Yu V. Roiter πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 386 KB πŸ‘ 3 views

The reactivity of both the peroxide (2-tert-butylperoxy-2-methyl-5-hexene-3-yne) and hydroperoxide (2-hydroperoxy-2-methyl-5-hexene-3-yne) monomers in the radical copolymerization was compared. Using the Alfrey-Price Q and e scheme, Hammett correlations, and MNDO quantum-chemical model it was shown