✦ LIBER ✦

The Electronic Spectrum of Germanium Monosulfide: Rotational Structure in the A1Π–X1Σ+ Transition in 70GeS

✍ Scribed by B.J. Shetty; Sunanda Krishnakumar; T.K. Balasubramanian

Publisher: Elsevier Science
Year: 2001
Tongue: English
Weight: 208 KB
Volume: 207
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.2001.8303

No coin nor oath required. For personal study only.

✦ Synopsis

The emission spectrum of the specific isotopomer 70 GeS was excited in a microwave (2450-MHz) discharge and the A 1 -X 1 + transition (270-430 nm) was photographed under high resolution on a 10.6-m Ebert grating spectrograph. The rotational analysis of 43 bands led to the determination of accurate vibrational and rotational constants. Making use of these constants, the potential energy curves for the A 1 and X 1 + states were generated by the RKR method and Franck-Condon factors and r -centroids were computed for the bands analyzed. The present extensive high-resolution study has revealed only a few localized perturbations in the A 1 (v = 4, 5, 9) vibronic states, which contrasts with the situation in the isovalent molecules such as GeO, SiS, and SiSe.

📜 SIMILAR VOLUMES

Transition Probabilities in the B1Σ+–X1Σ

Transition Probabilities in the B1Σ+–X1Σ+ and the B1Σ+–A1Π Electronic Systems of MgO

✍ John W. Daily; Christopher Dreyer; Angel Abbud-Madrid; Melvyn C. Branch 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 264 KB

Transition probabilities for the B 1 + -X 1 + and the B 1 + -A 1 electronic systems are presented for v = 0-4 and J = 0-150 in each electronic state. The functional form of the electronic transition moment for the B-X transition is taken from published ab initio results. The B-A moment is assumed to

A New Transition in the Spectrum of YCl:

A New Transition in the Spectrum of YCl: Rotational Analysis of theK1Π–X1Σ+UV Band System

✍ Ju Xin; Lennart Klynning 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 91 KB

The absorption spectrum of the yttrium monochloride molecule (YCl) produced in a King-type furnace has been recorded at high resolution using a 5-m Fastie spectrograph. A new band system in the UV region (centered at 3291 A ˚) has been found and rotationally analyzed. The transition has been assigne

The Electronic Structure and Spectrum of

The Electronic Structure and Spectrum of RhC: New Bands in the 400–500 nm Region, Interacting 2Σ+ and 2Π States, and Deperturbation

✍ W.J. Balfour; S.G. Fougère; R.F. Heuff; C.X.W. Qian; C. Zhou 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 349 KB

Rhodium monocarbide (RhC) molecules were generated using a laser ablation/supersonic molecular beam source. Laser-induced and dispersed-fluorescence (DF) techniques were used to study the visible spectrum between 400 and 530 nm. Rh(12)C/Rh(13)C isotope shifts, DF, and excited level lifetime measurem