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The Electronic Fine Structure of Co (11)-Complexes with Schiff-Base Ligands

✍ Scribed by Claude Daul; Jacques Weber

Publisher
John Wiley and Sons
Year
1982
Tongue
German
Weight
581 KB
Volume
65
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

Multiple‐scattering‐Xα MO‐calculations are reported for Co (acacen). The results are essentially in agreement with extended Hückel calculations and EPR. data. Particular emphasis has been placed on the calculation of the electronic structure and one‐electron properties, i.e. state energies diagram, spin‐orbit coupling and hyperfine coupling based on a ligand field interpretation of the Xα‐results, which allow to rationalize the main features of the EPR. spectra.

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✍ Bogusława Je·owska-Trzebiatowska; Julia Jezierska 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 303 KB

## Osovanadium(lV) compleszs with Schiff bases (bi-, tri-and tctmdentate Lignds) were investigated by EPR. On the basis of the experimental spin hamiltonian parameters the dependences of the chemical bond on the @aand nature as well 3s solvent character were obtairxd. The isotropic contact term is