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Electron paramagnetic resonance studies of oxovanadium(IV) complexes with Schiff bases as ligands

✍ Scribed by Bogusława Je·owska-Trzebiatowska; Julia Jezierska

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
303 KB
Volume
34
Category
Article
ISSN
0009-2614

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✦ Synopsis

Osovanadium(lV)

compleszs with Schiff bases (bi-, tri-and tctmdentate Lignds) were investigated by EPR. On the basis of the experimental spin hamiltonian parameters the dependences of the chemical bond on the @aand nature as well 3s solvent character were obtairxd. The isotropic contact term is a measure of covalency for this type of compound. Zero-field splitting panmeters were obtained for dimeric complexes of tridentate Schiff bases.

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