The cathodic potential-decay process on platinum electrodes in oleums has been investigated by means of a rotating disk. The non-steady parameters are compared with those already reported under steady-state conditions, Both results are discussed in terms of a general reaction mechanism comprising va
The electrolysis of fuming sulphuric acids
✍ Scribed by A.J. Arvía; J.S.W. Carrozza
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- English
- Weight
- 625 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0013-4686
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📜 SIMILAR VOLUMES
&&act-Anodic and cathodic processe s involved in the electrolysis of diBerent oleums were studied on platinum rotating disk electrodes at 25 and 5O"C, in a range of rotation speeds from 260 to 2000 'pm. Anodic processes do not change with the rate of stirring. The cathodic process occurring at low
Kinetic parameters related to the anodic and cathodic processes in the electrolysis of fuming sulphuric acids on bright platinum and platinii platinum electrodes have been established, the electrolyte bemg kept at rest. Experiments cover temperatures from 25 to 70°C and oleums with a stdphur trioxtd
## Production of Organic Acids by Electrolysis.--Bartoli and Papasogli have lately published some curious electrolytic experiments, They employed as eleotrodes, in a water voltametre, carbons of coke or ~)f wood purified by chlorine, and noticed that the carbons were attac, ked,