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The electrodeposition of aluminium from molten aluminium chloride/sodium chloride

✍ Scribed by R. C. Howie; D. W. Macmillan


Publisher
Springer
Year
1972
Tongue
English
Weight
1023 KB
Volume
2
Category
Article
ISSN
0021-891X

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Passivation of the aluminium cathode dur
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The kinetics of aluminium deposition from NaCI-AICl, melts (c,,,,, < 10 mol%) contained in alumina crucibles was studied by linear sweep voltammetry and potential step amperometry at temperatures around 820Β°C. At low concentrations (r,,,, I c 0.4 mol %) the reduction of AlCl, on iiquid aluminium has

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The kinetics of aluminium deposition from NaCI-AICl, and NaCl-KCI-AlCI, melts (cata, -=z 0.4 mol %) was studied by linear sweep ~oltammetry and potential step ampero.nctry. The reduction of AK& on tungsten and aluminium elcctrodcs was found to be diffusion controlled. The diffusion coefficients of A