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The electrochemistry of organotellurium compounds—III. The electrochemistry of triphenyltellurium chloride

✍ Scribed by Y. Liftman; M. Albeck


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
307 KB
Volume
29
Category
Article
ISSN
0013-4686

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✦ Synopsis


The electrochemical behaviour of Ph,TeCl in methylene chloride, containing tetrabutylammonium perchlorate (TBAP), at a platinum electrode has been studied. It is shown that Ph,TeCI is oxidized to Ph,(Cl)TeTePh,(CI) and reduced either in a one electron reaction to Ph3TeTePh, or in a two electron reaction to Ph,TeH. The electrochemical reactions depend on the concentration of Ph,TeCl in the solution, on the rate of rotation of the electrode and on the rate of the potential scan.


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