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The electrochemistry of organotellurium compounds—II. The electrochemistry of tellurides, diorganyltellurium dichlorides and diperchlorates

✍ Scribed by Y. Liftman; M. Albeck

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
384 KB
Volume
28
Category
Article
ISSN
0013-4686

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✦ Synopsis

The electrochemical hchaviour of tellurides. diorganyltellurium dichlorides and diperchlorates in methylene chloride or acctonitrile containing tetrabutylammonium pet-chlorate (TBAP) or lithium perchlorate (LEIO,) has heen studied. Various electrochemical techniques such as linear potential scan, cyclic voltammetry, controlled potential coulometry and a simultaneous coulometry-esr spectroscopy were applied. It was found that the dichlorides and the diperchlorates can he electrochemically reduced lo the corresponding tellurides in an electron-transfer reaction preceding a disproportionation and vice uerso.

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