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The electrochemistry of organic sulfur compounds: I. The 1,6,6aIVS-trithiapentalene-dimer redox couple

โœ Scribed by Carl Th. Pedersen; Ole Hammerich; Vernon D. Parker

Book ID
104149096
Publisher
Elsevier Science
Year
1972
Weight
171 KB
Volume
38
Category
Article
ISSN
0022-0728

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โœฆ Synopsis

The electrolytic behaviour of organic sulfur compounds has received very little attention 1. A notable exception can be found in the anodic reactions of tetrathioethylenes and related compounds recently described 2'3. As part of our continuing program in organic sulfur chemistry, we have examined the anodic behaviour of a series of compounds containing the trithiapentalene ring system (I) and report here the reversible conversion of these compounds to dication dimers (II)* linked by disulfide bonds.

* The systematic name of compound (IIa), for example, if /?,/~'-dithio-bis(3-styryl-5-phenyl-l,2dithiolylium)perchlorate.

๐Ÿ“œ SIMILAR VOLUMES

The electrochemistry of organic sulfur c
The electrochemistry of organic sulfur compounds. Part II. Cathodic reduction of 1,2-dithiolylium ions, redox analogy to the tropylium-bitropenyl system.
โœ Carl Th. Pedersen; Vernon D. Parker ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 185 KB

We have observed that cathodic reduction of several 1,2-dithiolylium ions (I) in acetonitrile at a platinum electrode is accompanied by the formation of the dimers (II). This reaction is remarkably efficient with coulometric n 1.

Electrochemistry of organic sulfur compo
Electrochemistry of organic sulfur compounds V. a polarographic study on the anodic oxidation of phenyl sulfides
โœ Sigeru Torii; Kenji Uneyama; Kozo Iida; Kazuo Sasaki ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 192 KB

This paper describes a total analysis of polarograms in the oxidation of phenyl sulfides along uith a discussion based on complete products analysis, 3) since such electrochemical studies are required to establish a reliable theory on the mechanism of the anodic process. 4,5) Polarograms of sulfides